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How Is Carbon Dioxide Stored in Carbon Capture?

Published in Carbon Capture Storage 4 mins read

Carbon dioxide (CO2) captured from industrial sources is primarily stored by injecting it deep underground into secure geological formations, where it remains permanently trapped away from the atmosphere.

What is Carbon Capture and Storage (CCS)?

Carbon Capture and Storage (CCS) is a critical technology designed to prevent large quantities of CO2, a potent greenhouse gas, from entering the atmosphere. It involves three main stages:

  1. Capture: Separating CO2 from other gases produced in industrial processes or power generation.
  2. Transport: Moving the captured CO2, often via pipelines, to a suitable storage site.
  3. Storage: Permanently sequestering the CO2 deep underground.

This process is essential for decarbonizing hard-to-abate sectors and achieving global climate goals.

Primary Methods for CO2 Storage

The captured CO2, once compressed into a dense, fluid-like state, is typically stored using one of several methods:

Geological Storage

Geological storage involves injecting CO2 into porous rock formations hundreds to thousands of meters beneath the Earth's surface. These formations are capped by impermeable rock layers, which act as a seal to prevent the CO2 from migrating upwards. The three main types of geological storage sites are:

  • Deep Saline Aquifers: These are underground geological formations characterized by vast expanses of porous, sedimentary rock filled with salt water. CO2 can be injected into these formations and stored permanently. Saline aquifers are recognized for having the largest identified storage potential among all forms of engineered CCS, offering immense capacity for CO2 sequestration globally. The CO2 is injected deep beneath potable water sources, ensuring safety. For more information, explore resources on geological sequestration.
  • Depleted Oil and Gas Reservoirs: These are formations that once held oil and natural gas and have undergone extensive exploration and production. Their geological characteristics (proven traps, well-understood geology, existing infrastructure) make them suitable for CO2 storage. Injecting CO2 into these reservoirs can also sometimes enhance oil recovery (known as CO2-EOR), providing an economic incentive.
  • Unmineable Coal Seams: In some cases, CO2 can be injected into deep, unmineable coal seams. The CO2 adsorbs to the coal, displacing methane (CH4) that is naturally present, which can then be captured and utilized. While offering storage potential, the capacity is generally less than saline aquifers or depleted reservoirs.

Mineral Carbonation

Also known as mineral storage, this method involves reacting CO2 with naturally occurring metal oxides found in certain silicate minerals (e.g., olivine, serpentine) to form stable carbonate minerals. This process mimics natural weathering but is accelerated. The resulting carbonates are environmentally benign and extremely stable, providing a permanent and irreversible form of storage. While promising for its permanence, it is currently more energy-intensive and less developed for large-scale application than geological storage.

How CO2 Stays Trapped Underground (Mechanisms)

Within geological formations, CO2 is trapped through a combination of mechanisms that ensure its long-term isolation:

  • Structural Trapping: This is the primary mechanism, where CO2 rises within the porous rock until it is physically blocked and contained by an overlying impermeable layer of caprock, much like how oil and gas are naturally trapped.
  • Residual Trapping: As CO2 moves through the pore spaces of the rock, some of it gets left behind as disconnected, immobile droplets. This occurs due to capillary forces, similar to how water is held in a sponge.
  • Solubility Trapping: Over time, the injected CO2 dissolves into the formation water (brine) present in the porous rock. This creates a denser, CO2-rich brine that tends to sink, further reducing the potential for upward migration.
  • Mineral Trapping: In the longest-term process, the dissolved CO2 can react with the minerals in the rock and the formation water to precipitate new, stable carbonate minerals. This chemically converts the CO2 into a solid, permanent form, ensuring virtually irreversible storage over thousands of years. Learn more about the science of CO2 storage.

Ensuring Safe and Permanent Storage

The safety and permanence of CO2 storage are paramount. Extensive site characterization, rigorous risk assessments, and comprehensive monitoring programs are implemented to ensure that CO2 remains securely underground. Monitoring techniques include seismic surveys, wellbore integrity checks, and atmospheric sensing to detect any potential leakage, ensuring environmental safety and public confidence in CCS technology.

Storage Methods Overview

Storage Method Description Permanence Current Status Key Advantage
Deep Saline Aquifers Porous sedimentary rock formations filled with salt water, sealed by impermeable caprock. High Commercial Largest storage capacity globally
Depleted Oil & Gas Reservoirs Former oil and gas fields with proven trapping mechanisms and existing infrastructure. High Commercial Well-understood geology, potential for EOR
Unmineable Coal Seams Deep coal seams where CO2 adsorbs to the coal, displacing methane. Moderate Pilot/Research Potential for methane recovery
Mineral Carbonation CO2 reacts with silicate minerals to form stable carbonate minerals. Very High Research/Pilot Irreversible, solid form of storage