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What is the conjugate acid of AsH3?

Published in Chemical Acid-Base Theory 2 mins read

The exact answer is AsH4+, also known as the arsonium ion.

Understanding Conjugate Acids and Bases

In chemistry, the concept of conjugate acids and bases is fundamental to the Brønsted-Lowry acid-base theory. This theory defines acids and bases based on their ability to donate or accept protons (H+ ions).

Key principles include:

  • Acids are proton donors: They lose an H+ ion.
  • Bases are proton acceptors: They gain an H+ ion.
  • When an acid donates a proton, it forms its conjugate base.
  • When a base accepts a proton, it forms its conjugate acid.

Essentially, a conjugate acid-base pair consists of two species that differ by only one proton (H+).

The Chemistry of AsH3

Arsine (AsH3) is a molecule with a pyramidal structure, similar to ammonia (NH3). Like ammonia, AsH3 possesses a lone pair of electrons on the central arsenic atom, which allows it to act as a proton acceptor. This characteristic enables AsH3 to function as a Brønsted-Lowry base.

Formation of the Conjugate Acid

When AsH3 acts as a base, it accepts a proton (H+) from an acid. The addition of this proton results in the formation of its conjugate acid.

The reaction demonstrating the formation of the conjugate acid is:

AsH3 (base) + H+ (proton) → AsH4+ (conjugate acid)

The resulting ion, AsH4+, is called the arsonium ion. It carries a positive charge because it has gained a positively charged proton.

The Conjugate Base of AsH3

While the question specifically asks for the conjugate acid, it's insightful to also understand the conjugate base of AsH3, which is AsH2-. This illustrates AsH3's potential to also act as a very weak acid, donating a proton.

The reaction demonstrating the formation of the conjugate base is:

AsH3 (acid) → AsH2- (conjugate base) + H+ (proton)

This dual behavior indicates that AsH3 can exhibit amphoteric properties, acting as both a very weak acid and a base, depending on the chemical environment.

Summary of AsH3 Acid-Base Pairs

The table below summarizes the acid-base relationships involving AsH3:

Species Role Corresponding Pair
AsH3 Brønsted-Lowry Base AsH4+ (Conjugate Acid)
AsH3 Brønsted-Lowry Acid AsH2- (Conjugate Base)

Therefore, the conjugate acid of AsH3 is AsH4+, formed when AsH3 accepts a proton.