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What is the old name of HCl?

Published in Chemical History 3 mins read

The old name for HCl is muriatic acid. This term reflects its historical connection to salt and brine and is still sometimes used today.

Understanding Muriatic Acid

Historically, chemicals were often named based on their origin or the raw materials from which they were derived. "Muriatic acid" is a prime example of this practice. The word "muriatic" comes from the Latin word "muria," which means "brine" or "pickle." This etymology directly links the acid to common salt (sodium chloride), from which hydrochloric acid can be produced.

Historical Context and Other Names

Before it was formally known as hydrochloric acid, HCl had several names that shed light on its discovery and early understanding:

  • Muriatic Acid: This was the most prevalent old name for the aqueous solution we now call hydrochloric acid.
  • Marine Acid Air: Interestingly, the gaseous form of HCl was known as marine acid air. This name also shares the same linguistic root as muriatic acid, referring to its association with "marine salt" or sea salt.
  • Spirit of Salt: Another common historical name was "spirit of salt," further emphasizing its derivation from common salt. Alchemists and early chemists often used this term.

Etymology and Significance

The naming convention highlights how early chemists perceived the substance. The term "muriatic" literally signifies "pertaining to brine or salt," which was a crucial clue to its composition and origin before hydrogen and chlorine were fully understood as its constituent elements.

Modern vs. Historical Terminology

The shift from "muriatic acid" to "hydrochloric acid" reflects advancements in chemical understanding. Once it was determined that the acid was composed of hydrogen and chlorine, the systematic name "hydrochloric acid" was adopted to accurately describe its elemental composition.

Historical Name Modern Name Origin/Meaning
Muriatic Acid Hydrochloric Acid From Latin "muria" (brine, salt)
Marine Acid Air Gaseous Hydrogen Chloride Gaseous form linked to marine salt
Spirit of Salt Hydrochloric Acid Derived from common salt

Current Use of the Term

While "hydrochloric acid" is the scientifically recognized and preferred name, the term muriatic acid is still encountered in various commercial and industrial settings. It typically refers to a slightly less pure, often diluted, form of hydrochloric acid available for specific practical applications.

Common applications where the term "muriatic acid" is still frequently used include:

  • pH Adjustment: Used to lower the pH in swimming pools.
  • Cleaning and Etching: Employed for etching concrete, cleaning masonry, and removing rust stains due to its strong corrosive properties.
  • Industrial Processes: Finds use in large-scale operations like metal pickling and ore processing.

Safety and Handling

Regardless of whether it's called muriatic acid or hydrochloric acid, it remains a strong, corrosive acid. Proper safety precautions, including appropriate personal protective equipment and ventilation, are essential when handling this chemical to prevent skin burns, eye damage, and respiratory irritation. For more detailed information, consult resources like the Hydrochloric Acid Wikipedia page or its entry on PubChem.