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What happens when magnesium chloride reacts with Sulphuric acid?

Published in Chemical Reactions 4 mins read

When magnesium chloride reacts with sulphuric acid, a double displacement reaction occurs, resulting in the formation of magnesium sulfate and hydrochloric acid. This is a common type of chemical reaction where the ions of two compounds swap places to form two new compounds.

The Primary Chemical Reaction

The reaction between magnesium chloride (MgCl2) and sulphuric acid (H2SO4) is typically carried out in an aqueous solution.

Understanding the Reactants

  • Magnesium Chloride (MgCl2): An ionic compound and a salt, usually found as a white crystalline solid or dissolved in water. It's soluble in water, dissociating into Mg²⁺ and Cl⁻ ions.
  • Sulphuric Acid (H2SO4): A strong mineral acid that is highly corrosive. In water, it dissociates into H⁺ and SO₄²⁻ ions.

The Double Displacement Process

In this reaction, the magnesium ions (Mg²⁺) from magnesium chloride combine with the sulfate ions (SO₄²⁻) from sulphuric acid to form magnesium sulfate. Simultaneously, the hydrogen ions (H⁺) from sulphuric acid combine with the chloride ions (Cl⁻) from magnesium chloride to form hydrochloric acid.

The balanced chemical equation for this reaction is:

MgCl₂(aq) + H₂SO₄(aq) → MgSO₄(aq) + 2HCl(aq)

This equation indicates that one mole of magnesium chloride reacts with one mole of sulphuric acid to produce one mole of magnesium sulfate and two moles of hydrochloric acid.

Products Formed

The two products generated from this reaction have distinct properties and applications:

  • Magnesium Sulfate (MgSO₄):

    • Often known as Epsom salt, it's a white, crystalline solid highly soluble in water.
    • It has various uses, including:
      • Medicinal: Used as a laxative, to treat magnesium deficiency, and as a soak for muscle aches and pains.
      • Agricultural: Employed as a fertilizer to correct magnesium or sulfur deficiencies in soil.
      • Industrial: Used in various chemical processes.
    • You can learn more about Magnesium Sulfate on Wikipedia.
  • Hydrochloric Acid (HCl):

    • A strong, corrosive mineral acid.
    • It's a clear, colorless solution with a pungent odor.
    • Highly acidic: It has a very low pH and can cause severe burns upon contact.
    • Industrial uses: Vital in steel pickling, organic compound production, pH control, and regeneration of ion exchangers.
    • Further information can be found on Hydrochloric Acid's Wikipedia page.

Practical Insights and Further Reactions

The formation of hydrochloric acid is significant due to its corrosive nature. In industrial settings or experimental contexts, the strong acid produced often needs to be neutralized for safety and environmental reasons.

Neutralization of Hydrochloric Acid

As highlighted in relevant processes, the two moles of hydrochloric acid produced can be neutralized using a base, such as calcium hydroxide (Ca(OH)₂). This is a classic acid-base neutralization reaction.

The reaction for neutralizing hydrochloric acid with calcium hydroxide is:

Ca(OH)₂(aq) + 2HCl(aq) → CaCl₂(aq) + 2H₂O(l)

In this neutralization step:

  • Calcium Hydroxide (Ca(OH)₂): A moderately strong base, also known as slaked lime.
  • Products:
    • Calcium Chloride (CaCl₂): A common salt used as a desiccant, in road de-icing, and as a food additive.
    • Water (H₂O): A neutral compound.

This subsequent reaction effectively converts the hazardous strong acid (HCl) into a relatively benign salt (CaCl₂) and water, making the solution safer to handle and dispose of.

Summary of the Reaction

Aspect Description
Reactants Magnesium Chloride (MgCl₂) and Sulphuric Acid (H₂SO₄)
Reaction Type Double Displacement Reaction
Primary Equation MgCl₂(aq) + H₂SO₄(aq) → MgSO₄(aq) + 2HCl(aq)
Products Magnesium Sulfate (MgSO₄) and Hydrochloric Acid (HCl)
Significance Produces a useful salt (Magnesium Sulfate) and a strong acid (Hydrochloric Acid) which often requires further neutralization.
Neutralization Ca(OH)₂(aq) + 2HCl(aq) → CaCl₂(aq) + 2H₂O(l) (if Calcium Hydroxide is used to neutralize the HCl)

Safety Considerations

When performing this reaction, particularly in a laboratory or industrial setting, it is crucial to observe strict safety protocols due to the involvement of sulphuric acid and the production of hydrochloric acid:

  • Personal Protective Equipment (PPE): Always wear safety goggles, gloves, and a lab coat to protect against splashes and chemical burns.
  • Ventilation: Work in a well-ventilated area or under a fume hood, as acid fumes can be irritating and hazardous.
  • Handling Acids: Always add acid slowly to water (never water to acid) when diluting, and handle concentrated acids with extreme care.
  • Waste Disposal: Ensure all chemical waste is disposed of according to local regulations, often requiring neutralization before disposal.

In conclusion, the reaction between magnesium chloride and sulphuric acid is a straightforward double displacement, yielding magnesium sulfate and hydrochloric acid. The resulting hydrochloric acid, being a strong acid, frequently necessitates further neutralization for safe handling and environmental compliance.