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What is the common name of Cu2+?

Published in Copper Ion Nomenclature 3 mins read

The common name of Cu2+ is the cupric ion.

Understanding Cupric Ion

The term "cupric" is a traditional, common name used to denote copper in its +2 oxidation state. This nomenclature system is often referred to as the "ous/ic" system, where "-ic" is used for the higher oxidation state and "-ous" for the lower one when an element exhibits two common oxidation states.

For copper, these are:

  • Cu+: Known as the cuprous ion.
  • Cu2+: Known as the cupric ion.

The cupric ion (Cu2+) is given this name because it possesses a higher charge compared to the cuprous ion (Cu+). This distinction based on charge is a key aspect of this older naming convention.

Systematic IUPAC Naming

While "cupric ion" is widely understood and commonly used, especially in older texts and some industries, the modern systematic naming convention established by the International Union of Pure and Applied Chemistry (IUPAC) uses Roman numerals to indicate the oxidation state.

Under IUPAC rules:

  • Cu+ is named Copper(I) ion.
  • Cu2+ is named Copper(II) ion.

Both "cupric ion" and "copper(II) ion" refer to the same chemical species. The systematic name is preferred for clarity and to avoid ambiguity, especially for elements with more than two common oxidation states. However, the common name "cupric" remains prevalent.

Key Characteristics of the Cu2+ Ion

The cupric ion is a common and important species in chemistry and biology. Here are some of its characteristics:

  • Color: Solutions containing Cu2+ ions are typically blue or blue-green due to their electronic configuration, which allows for light absorption in the red-orange part of the spectrum.
  • Presence: It is found in many minerals, salts, and biological systems. For instance, copper sulfate (CuSO4) is a common compound containing the cupric ion.
  • Role: Copper is an essential trace element for living organisms, where it plays a role in enzymes and electron transfer processes, often cycling between its Cu+ and Cu2+ forms.

Comparison of Copper Ions

To further clarify the naming, here's a quick comparison between the two common oxidation states of copper:

Characteristic Cu+ (Lower Oxidation State) Cu2+ (Higher Oxidation State)
Common Name Cuprous ion Cupric ion
Systematic Name Copper(I) ion Copper(II) ion
Charge +1 +2
Typical Color Often colorless or red Blue or blue-green
Example Compound Cuprous chloride (CuCl) Copper sulfate (CuSO4)

For more detailed information on copper's chemistry, you can explore resources like the Royal Society of Chemistry.