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Is there a type of fire that can burn underwater?

Published in Underwater Combustion 3 mins read

Yes, there are specific types of chemical reactions that produce heat and light, akin to fire, and can burn underwater. These reactions do not rely on atmospheric oxygen but instead utilize oxygen from other sources, such as water itself or integrated oxidizers within the fuel.

Understanding Underwater Combustion

Traditional fire requires three elements: fuel, heat, and an oxidizer (typically oxygen from the air). Underwater, the absence of atmospheric oxygen prevents most common fires. However, certain substances can undergo exothermic reactions in a water environment because they:

  • React directly with water: Some elements, like alkali metals, react violently with water to release hydrogen gas and heat, which can ignite the hydrogen.
  • Contain their own oxidizer: Some compounds are formulated to include both a fuel and an oxygen-rich compound, allowing them to burn independently of external oxygen sources.
  • Extract oxygen from water molecules: Certain materials are so reactive that they can strip oxygen directly from water molecules, sustaining combustion.

Magnesium: A Notable Example

One of the most well-known examples of a substance that can burn underwater is magnesium. When magnesium ignites, it burns intensely bright and can continue to burn even submerged in water.

  • Magnesium torches are a practical application of this phenomenon. These torches are specifically designed to leverage magnesium's ability to combust underwater and in various weather conditions. They produce a brilliant light source and are notably used for emergency illumination in applications such as railroad systems, providing visibility when conventional light sources might fail or be impractical.
  • The reaction involves magnesium reacting with water to produce magnesium oxide and hydrogen gas, releasing a significant amount of heat and light. The high heat generated can even decompose the water molecules, providing the necessary oxygen for the reaction to continue.

Other Materials and Applications

While magnesium is a prominent example, other materials and formulations are designed for underwater combustion or extreme reactivity with water:

  • Alkali Metals (e.g., Sodium, Potassium): These metals react violently with water, producing hydrogen gas and enough heat to ignite it. However, their extreme reactivity makes them highly dangerous and not typically used for controlled underwater "fire."
  • Thermite Reactions: While not typically burning in water, some highly exothermic reactions can be initiated underwater if the components are kept dry until ignition.
  • Specialized Pyrotechnics: Some military or specialized pyrotechnic devices are designed to burn or produce light underwater for signaling or destructive purposes.

In summary, the concept of "fire" underwater is possible through specific chemical reactions that bypass the need for atmospheric oxygen, with magnesium being a prime example utilized in practical tools like underwater torches.